Two-center interferences in photoionization of a dissociating H2+ molecule
Picón Álvarez, Antonio (University of Colorado at Boulder. Department of Physics)
Bahabad, A. (University of Colorado at Boulder. Department of Physics)
Kapteyn, H. C. (University of Colorado at Boulder. Department of Physics)
Murnane, M. M. (University of Colorado at Boulder. Department of Physics)
Becker, A. (University of Colorado at Boulder. Department of Physics)
American Physical Society

Data:	2011
Resum:	We analyze two-center interference effects in the yields of ionization of a dissociating hydrogen molecular ion by an ultrashort vuv laser pulse. To this end, we performed numerical simulations of the time-dependent Schrödinger equation for a H2+ model ion interacting with two time-delayed laser pulses. The scenario considered corresponds to a pump-probe scheme, in which the first (pump) pulse excites the molecular ion to the first excited dissociative state and the second (probe) pulse ionizes the electron as the ion dissociates. The results of our numerical simulations for the ionization yield as a function of the time delay between the two pulses exhibit characteristic oscillations due to interferences between the partial electron waves emerging from the two protons in the dissociating hydrogen molecular ion. We show that the photon energy of the pump pulse should be in resonance with the σg−σu transition and the pump pulse duration should not exceed 5 fs in order to generate a well-confined nuclear wave packet. The spreading of the nuclear wave packet during the dissociation is found to cause a decrease of the amplitudes of the oscillations as the time delay increases. We develop an analytical model to fit the oscillations and show how dynamic information about the nuclear wave packet, namely, velocity, mean internuclear distance, and spreading, can be retrieved from the oscillations. The predictions of the analytical model are tested well against the results of our numerical simulations.
Drets:	Tots els drets reservats.
Llengua:	Anglès
Document:	Article ; recerca ; Versió publicada
Publicat a:	Physical review. A, Vol. 83, Issue 1 (January 2011) , p. 013414-1-013414-9, ISSN 1050-2947

DOI: 10.1103/PhysRevA.83.013414

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